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(Z)-(1,2-Dichlorovinyl)diphenylphosphine oxide
The title compound, C(14)H(11)Cl(2)OP, was synthesized by the reaction of diphenylphosphine oxide with 1,2-dichloroethyne under CuI catalysis. The reaction provided the Z isomer regioselectively. Two O—P—C bond angles [114.3 (1) and 112.5 (1)°] are significantly larger than the C—P—C [107.7 (1), 1...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200614/ https://www.ncbi.nlm.nih.gov/pubmed/22058922 http://dx.doi.org/10.1107/S1600536811030765 |