Cyclization of 5-hexynoic acid to 3-alkoxy-2-cyclohexenones

The one-pot cyclization of 5-hexynoic acid to produce 3-alkoxy-2-cyclohexenones proceeds in good yields (58–90%). 3-Hexynoic acid was converted to its acyl chloride with the aid of oxalyl chloride and was cyclized to 3-chloro-2-cyclohexenone upon addition of indium(III) chloride. Subsequent addition...

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Detalles Bibliográficos
Autores principales: Hylden, Anne T, Uzelac, Eric J, Ostojic, Zeljko, Wu, Ting-Ting, Sacry, Keely L, Sacry, Krista L, Xi, Lin, Jones, T Nicholas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201045/
https://www.ncbi.nlm.nih.gov/pubmed/22043242
http://dx.doi.org/10.3762/bjoc.7.155

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201045/
https://www.ncbi.nlm.nih.gov/pubmed/22043242
http://dx.doi.org/10.3762/bjoc.7.155

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