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A second monoclinic polymorph of bis­(2,2′-bipyridine-κ(2) N,N′)diiodido­manganese(II)

The Mn(II) ion in the title complex, [MnI(2)(C(10)H(8)N(2))(2)], is six-coordinated in a distorted cis-N(4)I(2)Mn octa­hedral environment by four N atoms of the two chelating 2,2′-bipyridine ligands and two iodide anions. As a result of the different trans effects of the N and I atoms, the Mn—N bond...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201270/
https://www.ncbi.nlm.nih.gov/pubmed/22065514
http://dx.doi.org/10.1107/S1600536811036051