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Electrostatic repulsion between the cations of (1-methyl-1H-imidazole-κN (3))(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)platinum(II) perchlorate nitromethane monosolvate prevents Pt⋯Pt interactions
The reaction between [Pt(terpy)Cl]·2H(2)O (terpy = 2′,2′′:6′,2′′-terpyridine) and 1-methylimidazole (MIm) in the presence of two equivalents of AgClO(4) in nitromethane yields the title compound, [Pt(C(15)H(11)N(3))(C(4)H(6)N(2))](ClO(4))(2)·CH(3)NO(2). The dicationic complexes are arranged in a s...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212152/ https://www.ncbi.nlm.nih.gov/pubmed/22090854 http://dx.doi.org/10.1107/S1600536811025475 |