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Electrostatic repulsion between the cations of (1-methyl-1H-imidazole-κN (3))(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)platinum(II) perchlorate nitro­methane monosolvate prevents Pt⋯Pt inter­actions

The reaction between [Pt(terpy)Cl]·2H(2)O (terpy = 2′,2′′:6′,2′′-terpyridine) and 1-methyl­imidazole (MIm) in the presence of two equivalents of AgClO(4) in nitro­methane yields the title compound, [Pt(C(15)H(11)N(3))(C(4)H(6)N(2))](ClO(4))(2)·CH(3)NO(2). The dicationic complexes are arranged in a s...

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Detalles Bibliográficos
Autores principales: Akerman, Matthew, Akerman, Kate, Jaganyi, Deogratius, Reddy, Desigan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212152/
https://www.ncbi.nlm.nih.gov/pubmed/22090854
http://dx.doi.org/10.1107/S1600536811025475