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[Bis(pyridin-2-ylmeth­yl) ether]trichlorido­rhodium(III) dichloro­methane monosolvate: unusual hydrolysis of the methyl­ene bridge in (pyrazolylmeth­yl)pyridine

In the title compound, [RhCl(3)(C(12)H(12)N(2)O)]·CH(2)Cl(2), the Rh(III) atom shows a slightly distorted octa­hedral geometry being coordinated by two N atoms and one O atom from the 2,2′-(oxydimethanedi­yl)dipyridine ligand and three Cl atoms. Two Cl atoms adopt a trans arrangement to the two pyri...

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Detalles Bibliográficos
Autores principales: Ojwach, Stephen O., Omondi, Bernard, Darkwa, James
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212169/
https://www.ncbi.nlm.nih.gov/pubmed/22090871
http://dx.doi.org/10.1107/S1600536811027644