[Bis(pyridin-2-ylmeth­yl) ether]trichlorido­rhodium(III) dichloro­methane monosolvate: unusual hydrolysis of the methyl­ene bridge in (pyrazolylmeth­yl)pyridine

In the title compound, [RhCl(3)(C(12)H(12)N(2)O)]·CH(2)Cl(2), the Rh(III) atom shows a slightly distorted octa­hedral geometry being coordinated by two N atoms and one O atom from the 2,2′-(oxydimethanedi­yl)dipyridine ligand and three Cl atoms. Two Cl atoms adopt a trans arrangement to the two pyri...

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Detalles Bibliográficos
Autores principales: Ojwach, Stephen O., Omondi, Bernard, Darkwa, James
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212169/
https://www.ncbi.nlm.nih.gov/pubmed/22090871
http://dx.doi.org/10.1107/S1600536811027644
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author Ojwach, Stephen O.
Omondi, Bernard
Darkwa, James
author_facet Ojwach, Stephen O.
Omondi, Bernard
Darkwa, James
author_sort Ojwach, Stephen O.
collection PubMed
description In the title compound, [RhCl(3)(C(12)H(12)N(2)O)]·CH(2)Cl(2), the Rh(III) atom shows a slightly distorted octa­hedral geometry being coordinated by two N atoms and one O atom from the 2,2′-(oxydimethanedi­yl)dipyridine ligand and three Cl atoms. Two Cl atoms adopt a trans arrangement to the two pyridyl N atoms, while the third Cl atom and the O atoms occupy the axial site. The Rh—Cl bonds that are trans to the pyridyl N atoms are slightly longer than the Rh—Cl bond distance trans to the O atom.
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spelling pubmed-32121692011-11-16 [Bis(pyridin-2-ylmeth­yl) ether]trichlorido­rhodium(III) dichloro­methane monosolvate: unusual hydrolysis of the methyl­ene bridge in (pyrazolylmeth­yl)pyridine Ojwach, Stephen O. Omondi, Bernard Darkwa, James Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RhCl(3)(C(12)H(12)N(2)O)]·CH(2)Cl(2), the Rh(III) atom shows a slightly distorted octa­hedral geometry being coordinated by two N atoms and one O atom from the 2,2′-(oxydimethanedi­yl)dipyridine ligand and three Cl atoms. Two Cl atoms adopt a trans arrangement to the two pyridyl N atoms, while the third Cl atom and the O atoms occupy the axial site. The Rh—Cl bonds that are trans to the pyridyl N atoms are slightly longer than the Rh—Cl bond distance trans to the O atom. International Union of Crystallography 2011-07-16 /pmc/articles/PMC3212169/ /pubmed/22090871 http://dx.doi.org/10.1107/S1600536811027644 Text en © Ojwach et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ojwach, Stephen O.
Omondi, Bernard
Darkwa, James
[Bis(pyridin-2-ylmeth­yl) ether]trichlorido­rhodium(III) dichloro­methane monosolvate: unusual hydrolysis of the methyl­ene bridge in (pyrazolylmeth­yl)pyridine
title [Bis(pyridin-2-ylmeth­yl) ether]trichlorido­rhodium(III) dichloro­methane monosolvate: unusual hydrolysis of the methyl­ene bridge in (pyrazolylmeth­yl)pyridine
title_full [Bis(pyridin-2-ylmeth­yl) ether]trichlorido­rhodium(III) dichloro­methane monosolvate: unusual hydrolysis of the methyl­ene bridge in (pyrazolylmeth­yl)pyridine
title_fullStr [Bis(pyridin-2-ylmeth­yl) ether]trichlorido­rhodium(III) dichloro­methane monosolvate: unusual hydrolysis of the methyl­ene bridge in (pyrazolylmeth­yl)pyridine
title_full_unstemmed [Bis(pyridin-2-ylmeth­yl) ether]trichlorido­rhodium(III) dichloro­methane monosolvate: unusual hydrolysis of the methyl­ene bridge in (pyrazolylmeth­yl)pyridine
title_short [Bis(pyridin-2-ylmeth­yl) ether]trichlorido­rhodium(III) dichloro­methane monosolvate: unusual hydrolysis of the methyl­ene bridge in (pyrazolylmeth­yl)pyridine
title_sort [bis(pyridin-2-ylmeth­yl) ether]trichlorido­rhodium(iii) dichloro­methane monosolvate: unusual hydrolysis of the methyl­ene bridge in (pyrazolylmeth­yl)pyridine
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212169/
https://www.ncbi.nlm.nih.gov/pubmed/22090871
http://dx.doi.org/10.1107/S1600536811027644
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AT omondibernard bispyridin2ylmethylethertrichloridorhodiumiiidichloromethanemonosolvateunusualhydrolysisofthemethylenebridgeinpyrazolylmethylpyridine
AT darkwajames bispyridin2ylmethylethertrichloridorhodiumiiidichloromethanemonosolvateunusualhydrolysisofthemethylenebridgeinpyrazolylmethylpyridine

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