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[Bis(pyridin-2-ylmethyl) ether]trichloridorhodium(III) dichloromethane monosolvate: unusual hydrolysis of the methylene bridge in (pyrazolylmethyl)pyridine
In the title compound, [RhCl(3)(C(12)H(12)N(2)O)]·CH(2)Cl(2), the Rh(III) atom shows a slightly distorted octahedral geometry being coordinated by two N atoms and one O atom from the 2,2′-(oxydimethanediyl)dipyridine ligand and three Cl atoms. Two Cl atoms adopt a trans arrangement to the two pyri...
Autores principales: | Ojwach, Stephen O., Omondi, Bernard, Darkwa, James |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212169/ https://www.ncbi.nlm.nih.gov/pubmed/22090871 http://dx.doi.org/10.1107/S1600536811027644 |
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