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Enhanced clickability of doubly sterically-hindered aryl azides

Steric character is one of the most fundamental factors to determine the reactivity of the substrate in organic synthesis. In bimolecular reaction, the sterically-bulky group situated close to the reactive center generally prevents the approach of the reaction partner retarding the bond formation. T...

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Detalles Bibliográficos
Autores principales: Yoshida, Suguru, Shiraishi, Akira, Kanno, Kimiyuki, Matsushita, Takeshi, Johmoto, Kohei, Uekusa, Hidehiro, Hosoya, Takamitsu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3216569/
https://www.ncbi.nlm.nih.gov/pubmed/22355601
http://dx.doi.org/10.1038/srep00082