Penta­carbonyl-1κ(2) C,2κ(3) C-(μ-pyrazine-2,3-dithiol­ato-1:2κ(4) S,S′:S,S′)(trimethyl­phosphane-1κP)diiron(I)(Fe—Fe)

In the title compound, [Fe(2)(C(4)H(2)N(2)S(2))(C(3)H(9)P)(CO)(5)], the Fe(2)S(2) core adopts a butterfly conformation. The PMe(3) ligand is coordinated in the basal position, roughly cis to the Fe—Fe bond. The Fe—Fe distance of 2.4970 (6) Å is relatively short compared to those (ca 2.53 Å) found in...

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Detalles Bibliográficos
Autores principales: Gao, Shang, An, Chun-Ai, Duan, Qian, Jiang, Da-Yong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238657/
https://www.ncbi.nlm.nih.gov/pubmed/22199548
http://dx.doi.org/10.1107/S1600536811046770

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238657/
https://www.ncbi.nlm.nih.gov/pubmed/22199548
http://dx.doi.org/10.1107/S1600536811046770

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