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Pentacarbonyl-1κ(2) C,2κ(3) C-(μ-pyrazine-2,3-dithiolato-1:2κ(4) S,S′:S,S′)(trimethylphosphane-1κP)diiron(I)(Fe—Fe)
In the title compound, [Fe(2)(C(4)H(2)N(2)S(2))(C(3)H(9)P)(CO)(5)], the Fe(2)S(2) core adopts a butterfly conformation. The PMe(3) ligand is coordinated in the basal position, roughly cis to the Fe—Fe bond. The Fe—Fe distance of 2.4970 (6) Å is relatively short compared to those (ca 2.53 Å) found in...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238657/ https://www.ncbi.nlm.nih.gov/pubmed/22199548 http://dx.doi.org/10.1107/S1600536811046770 |
| _version_ | 1782219032030609408 |
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| author | Gao, Shang An, Chun-Ai Duan, Qian Jiang, Da-Yong |
| author_facet | Gao, Shang An, Chun-Ai Duan, Qian Jiang, Da-Yong |
| author_sort | Gao, Shang |
| collection | PubMed |
| description | In the title compound, [Fe(2)(C(4)H(2)N(2)S(2))(C(3)H(9)P)(CO)(5)], the Fe(2)S(2) core adopts a butterfly conformation. The PMe(3) ligand is coordinated in the basal position, roughly cis to the Fe—Fe bond. The Fe—Fe distance of 2.4970 (6) Å is relatively short compared to those (ca 2.53 Å) found in another monosubstituted diiron compound. A rigid planar dithiolate bridge is featured, with an angle of 2.78 (1)° between the Fe—Fe bond and the normal to the pyrazine-2,3-dithiolate plane. |
| format | Online Article Text |
| id | pubmed-3238657 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32386572011-12-23 Pentacarbonyl-1κ(2) C,2κ(3) C-(μ-pyrazine-2,3-dithiolato-1:2κ(4) S,S′:S,S′)(trimethylphosphane-1κP)diiron(I)(Fe—Fe) Gao, Shang An, Chun-Ai Duan, Qian Jiang, Da-Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(2)(C(4)H(2)N(2)S(2))(C(3)H(9)P)(CO)(5)], the Fe(2)S(2) core adopts a butterfly conformation. The PMe(3) ligand is coordinated in the basal position, roughly cis to the Fe—Fe bond. The Fe—Fe distance of 2.4970 (6) Å is relatively short compared to those (ca 2.53 Å) found in another monosubstituted diiron compound. A rigid planar dithiolate bridge is featured, with an angle of 2.78 (1)° between the Fe—Fe bond and the normal to the pyrazine-2,3-dithiolate plane. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238657/ /pubmed/22199548 http://dx.doi.org/10.1107/S1600536811046770 Text en © Gao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gao, Shang An, Chun-Ai Duan, Qian Jiang, Da-Yong Pentacarbonyl-1κ(2) C,2κ(3) C-(μ-pyrazine-2,3-dithiolato-1:2κ(4) S,S′:S,S′)(trimethylphosphane-1κP)diiron(I)(Fe—Fe) |
| title | Pentacarbonyl-1κ(2)
C,2κ(3)
C-(μ-pyrazine-2,3-dithiolato-1:2κ(4)
S,S′:S,S′)(trimethylphosphane-1κP)diiron(I)(Fe—Fe) |
| title_full | Pentacarbonyl-1κ(2)
C,2κ(3)
C-(μ-pyrazine-2,3-dithiolato-1:2κ(4)
S,S′:S,S′)(trimethylphosphane-1κP)diiron(I)(Fe—Fe) |
| title_fullStr | Pentacarbonyl-1κ(2)
C,2κ(3)
C-(μ-pyrazine-2,3-dithiolato-1:2κ(4)
S,S′:S,S′)(trimethylphosphane-1κP)diiron(I)(Fe—Fe) |
| title_full_unstemmed | Pentacarbonyl-1κ(2)
C,2κ(3)
C-(μ-pyrazine-2,3-dithiolato-1:2κ(4)
S,S′:S,S′)(trimethylphosphane-1κP)diiron(I)(Fe—Fe) |
| title_short | Pentacarbonyl-1κ(2)
C,2κ(3)
C-(μ-pyrazine-2,3-dithiolato-1:2κ(4)
S,S′:S,S′)(trimethylphosphane-1κP)diiron(I)(Fe—Fe) |
| title_sort | pentacarbonyl-1κ(2)
c,2κ(3)
c-(μ-pyrazine-2,3-dithiolato-1:2κ(4)
s,s′:s,s′)(trimethylphosphane-1κp)diiron(i)(fe—fe) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238657/ https://www.ncbi.nlm.nih.gov/pubmed/22199548 http://dx.doi.org/10.1107/S1600536811046770 |
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