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Undecacarbonyl-μ(2)-methanethiolato-μ(2)-[(pyridin-2-yl)methanethiolato]-μ(4)-sulfido-tetrairon(II)(2 Fe—Fe)
The title compound, [Fe(4)(C(6)H(6)NS)(CH(3)S)S(CO)(11)], comprises two butterfly-shaped sub-cluster cores, Fe(2)S(2)N and Fe(2)S(2), joined together by a spiro-type μ(4)-S atom. The (pyridin-2-yl)methanethiolate ligand is attached to the Fe(2)(CO)(5) unit in a μ-κN:κ(2) S mode, and the methanet...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238668/ https://www.ncbi.nlm.nih.gov/pubmed/22199559 http://dx.doi.org/10.1107/S1600536811047751 |