Undeca­carbonyl-μ(2)-methane­thiol­ato-μ(2)-[(pyridin-2-yl)methane­thiol­ato]-μ(4)-sulfido-tetra­iron(II)(2 Fe—Fe)

The title compound, [Fe(4)(C(6)H(6)NS)(CH(3)S)S(CO)(11)], com­prises two butterfly-shaped sub-cluster cores, Fe(2)S(2)N and Fe(2)S(2), joined together by a spiro-type μ(4)-S atom. The (pyridin-2-yl)methane­thiol­ate ligand is attached to the Fe(2)(CO)(5) unit in a μ-κN:κ(2) S mode, and the methane­t...

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Detalles Bibliográficos
Autores principales: Shi, Yao-Cheng, Lai, Liang, Shen, Wen-Bin, Yuan, Li-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238668/
https://www.ncbi.nlm.nih.gov/pubmed/22199559
http://dx.doi.org/10.1107/S1600536811047751
Descripción
Sumario:The title compound, [Fe(4)(C(6)H(6)NS)(CH(3)S)S(CO)(11)], com­prises two butterfly-shaped sub-cluster cores, Fe(2)S(2)N and Fe(2)S(2), joined together by a spiro-type μ(4)-S atom. The (pyridin-2-yl)methane­thiol­ate ligand is attached to the Fe(2)(CO)(5) unit in a μ-κN:κ(2) S mode, and the methane­thiol­ate ligand is coordinated to the Fe(2)(CO)(6) unit in a μ-κ(2) S fashion.

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