Undeca­carbonyl-μ(2)-methane­thiol­ato-μ(2)-[(pyridin-2-yl)methane­thiol­ato]-μ(4)-sulfido-tetra­iron(II)(2 Fe—Fe)

The title compound, [Fe(4)(C(6)H(6)NS)(CH(3)S)S(CO)(11)], com­prises two butterfly-shaped sub-cluster cores, Fe(2)S(2)N and Fe(2)S(2), joined together by a spiro-type μ(4)-S atom. The (pyridin-2-yl)methane­thiol­ate ligand is attached to the Fe(2)(CO)(5) unit in a μ-κN:κ(2) S mode, and the methane­t...

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Detalles Bibliográficos
Autores principales: Shi, Yao-Cheng, Lai, Liang, Shen, Wen-Bin, Yuan, Li-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238668/
https://www.ncbi.nlm.nih.gov/pubmed/22199559
http://dx.doi.org/10.1107/S1600536811047751
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author Shi, Yao-Cheng
Lai, Liang
Shen, Wen-Bin
Yuan, Li-Min
author_facet Shi, Yao-Cheng
Lai, Liang
Shen, Wen-Bin
Yuan, Li-Min
author_sort Shi, Yao-Cheng
collection PubMed
description The title compound, [Fe(4)(C(6)H(6)NS)(CH(3)S)S(CO)(11)], com­prises two butterfly-shaped sub-cluster cores, Fe(2)S(2)N and Fe(2)S(2), joined together by a spiro-type μ(4)-S atom. The (pyridin-2-yl)methane­thiol­ate ligand is attached to the Fe(2)(CO)(5) unit in a μ-κN:κ(2) S mode, and the methane­thiol­ate ligand is coordinated to the Fe(2)(CO)(6) unit in a μ-κ(2) S fashion.
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spelling pubmed-32386682011-12-23 Undeca­carbonyl-μ(2)-methane­thiol­ato-μ(2)-[(pyridin-2-yl)methane­thiol­ato]-μ(4)-sulfido-tetra­iron(II)(2 Fe—Fe) Shi, Yao-Cheng Lai, Liang Shen, Wen-Bin Yuan, Li-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(4)(C(6)H(6)NS)(CH(3)S)S(CO)(11)], com­prises two butterfly-shaped sub-cluster cores, Fe(2)S(2)N and Fe(2)S(2), joined together by a spiro-type μ(4)-S atom. The (pyridin-2-yl)methane­thiol­ate ligand is attached to the Fe(2)(CO)(5) unit in a μ-κN:κ(2) S mode, and the methane­thiol­ate ligand is coordinated to the Fe(2)(CO)(6) unit in a μ-κ(2) S fashion. International Union of Crystallography 2011-11-16 /pmc/articles/PMC3238668/ /pubmed/22199559 http://dx.doi.org/10.1107/S1600536811047751 Text en © Shi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Yao-Cheng
Lai, Liang
Shen, Wen-Bin
Yuan, Li-Min
Undeca­carbonyl-μ(2)-methane­thiol­ato-μ(2)-[(pyridin-2-yl)methane­thiol­ato]-μ(4)-sulfido-tetra­iron(II)(2 Fe—Fe)
title Undeca­carbonyl-μ(2)-methane­thiol­ato-μ(2)-[(pyridin-2-yl)methane­thiol­ato]-μ(4)-sulfido-tetra­iron(II)(2 Fe—Fe)
title_full Undeca­carbonyl-μ(2)-methane­thiol­ato-μ(2)-[(pyridin-2-yl)methane­thiol­ato]-μ(4)-sulfido-tetra­iron(II)(2 Fe—Fe)
title_fullStr Undeca­carbonyl-μ(2)-methane­thiol­ato-μ(2)-[(pyridin-2-yl)methane­thiol­ato]-μ(4)-sulfido-tetra­iron(II)(2 Fe—Fe)
title_full_unstemmed Undeca­carbonyl-μ(2)-methane­thiol­ato-μ(2)-[(pyridin-2-yl)methane­thiol­ato]-μ(4)-sulfido-tetra­iron(II)(2 Fe—Fe)
title_short Undeca­carbonyl-μ(2)-methane­thiol­ato-μ(2)-[(pyridin-2-yl)methane­thiol­ato]-μ(4)-sulfido-tetra­iron(II)(2 Fe—Fe)
title_sort undeca­carbonyl-μ(2)-methane­thiol­ato-μ(2)-[(pyridin-2-yl)methane­thiol­ato]-μ(4)-sulfido-tetra­iron(ii)(2 fe—fe)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238668/
https://www.ncbi.nlm.nih.gov/pubmed/22199559
http://dx.doi.org/10.1107/S1600536811047751
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