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{(R,S (Fc),S (Fc))-2′′-Bromo-2-[1-(dimethylamino)ethyl-κN]-1,1′′-biferrocene}trihydridoboron
The title structure, [Fe(2)(C(5)H(5))(2)(C(14)H(19)BBrN)], contains a chiral and asymmetrically 2,2′′-disubstituted biferrocene designed as precursor for enantioselective non-C (2)-symmetric biferrocenyldiphosphine catalysts. The mean bond lengths in the biferrocene unit are Fe—C = 2.048 (10) Å and...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238712/ https://www.ncbi.nlm.nih.gov/pubmed/22199589 http://dx.doi.org/10.1107/S1600536811049270 |