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[2,2′-Bis(diphenylphosphanyl)-1,1′-binaphthyl-κ(2) P,P′]chlorido(4-methylphenylsulfonyl-κS)palladium(II) dichloromethane trisolvate monohydrate
In the title compound, [Pd(C(7)H(7)O(2)S)Cl(C(44)H(32)P(2))]·3CH(2)Cl(2)·H(2)O, the geometry around the metal atom is distorted square planar, with a twist angle between the P—Pd—P and S—Pd—Cl planes of 28.11 (2)°. The two Pd—P bond lengths differ by about 0.04 Å and the biphosphane bite angle is sl...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238729/ https://www.ncbi.nlm.nih.gov/pubmed/22199606 http://dx.doi.org/10.1107/S1600536811049889 |