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[2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]chlorido(4-methyl­phenyl­sulfon­yl-κS)palladium(II) dichloro­methane tris­olvate monohydrate

In the title compound, [Pd(C(7)H(7)O(2)S)Cl(C(44)H(32)P(2))]·3CH(2)Cl(2)·H(2)O, the geometry around the metal atom is distorted square planar, with a twist angle between the P—Pd—P and S—Pd—Cl planes of 28.11 (2)°. The two Pd—P bond lengths differ by about 0.04 Å and the biphosphane bite angle is sl...

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Detalles Bibliográficos
Autores principales: Shrestha, Ruja, Brennessel, William W., Weix, Daniel J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238729/
https://www.ncbi.nlm.nih.gov/pubmed/22199606
http://dx.doi.org/10.1107/S1600536811049889
Descripción
Sumario:In the title compound, [Pd(C(7)H(7)O(2)S)Cl(C(44)H(32)P(2))]·3CH(2)Cl(2)·H(2)O, the geometry around the metal atom is distorted square planar, with a twist angle between the P—Pd—P and S—Pd—Cl planes of 28.11 (2)°. The two Pd—P bond lengths differ by about 0.04 Å and the biphosphane bite angle is slightly obtuse [92.92 (2)°]. There are three dichloro­methane and one water mol­ecule co-crystallized with the palladium mol­ecule, all with atoms in general positions. Alternating water and palladium mol­ecules form four-membered cyclic units through O—H⋯Cl and O—H⋯O hydrogen bonding. One of the dichloromethane solvent molecules is disordered over two positions in a 0.55:0.45 ratio.