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[2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]chlorido(4-methyl­phenyl­sulfon­yl-κS)palladium(II) dichloro­methane tris­olvate monohydrate

In the title compound, [Pd(C(7)H(7)O(2)S)Cl(C(44)H(32)P(2))]·3CH(2)Cl(2)·H(2)O, the geometry around the metal atom is distorted square planar, with a twist angle between the P—Pd—P and S—Pd—Cl planes of 28.11 (2)°. The two Pd—P bond lengths differ by about 0.04 Å and the biphosphane bite angle is sl...

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Detalles Bibliográficos
Autores principales: Shrestha, Ruja, Brennessel, William W., Weix, Daniel J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238729/
https://www.ncbi.nlm.nih.gov/pubmed/22199606
http://dx.doi.org/10.1107/S1600536811049889
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author Shrestha, Ruja
Brennessel, William W.
Weix, Daniel J.
author_facet Shrestha, Ruja
Brennessel, William W.
Weix, Daniel J.
author_sort Shrestha, Ruja
collection PubMed
description In the title compound, [Pd(C(7)H(7)O(2)S)Cl(C(44)H(32)P(2))]·3CH(2)Cl(2)·H(2)O, the geometry around the metal atom is distorted square planar, with a twist angle between the P—Pd—P and S—Pd—Cl planes of 28.11 (2)°. The two Pd—P bond lengths differ by about 0.04 Å and the biphosphane bite angle is slightly obtuse [92.92 (2)°]. There are three dichloro­methane and one water mol­ecule co-crystallized with the palladium mol­ecule, all with atoms in general positions. Alternating water and palladium mol­ecules form four-membered cyclic units through O—H⋯Cl and O—H⋯O hydrogen bonding. One of the dichloromethane solvent molecules is disordered over two positions in a 0.55:0.45 ratio.
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spelling pubmed-32387292011-12-23 [2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]chlorido(4-methyl­phenyl­sulfon­yl-κS)palladium(II) dichloro­methane tris­olvate monohydrate Shrestha, Ruja Brennessel, William W. Weix, Daniel J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(7)H(7)O(2)S)Cl(C(44)H(32)P(2))]·3CH(2)Cl(2)·H(2)O, the geometry around the metal atom is distorted square planar, with a twist angle between the P—Pd—P and S—Pd—Cl planes of 28.11 (2)°. The two Pd—P bond lengths differ by about 0.04 Å and the biphosphane bite angle is slightly obtuse [92.92 (2)°]. There are three dichloro­methane and one water mol­ecule co-crystallized with the palladium mol­ecule, all with atoms in general positions. Alternating water and palladium mol­ecules form four-membered cyclic units through O—H⋯Cl and O—H⋯O hydrogen bonding. One of the dichloromethane solvent molecules is disordered over two positions in a 0.55:0.45 ratio. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238729/ /pubmed/22199606 http://dx.doi.org/10.1107/S1600536811049889 Text en © Shrestha et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shrestha, Ruja
Brennessel, William W.
Weix, Daniel J.
[2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]chlorido(4-methyl­phenyl­sulfon­yl-κS)palladium(II) dichloro­methane tris­olvate monohydrate
title [2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]chlorido(4-methyl­phenyl­sulfon­yl-κS)palladium(II) dichloro­methane tris­olvate monohydrate
title_full [2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]chlorido(4-methyl­phenyl­sulfon­yl-κS)palladium(II) dichloro­methane tris­olvate monohydrate
title_fullStr [2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]chlorido(4-methyl­phenyl­sulfon­yl-κS)palladium(II) dichloro­methane tris­olvate monohydrate
title_full_unstemmed [2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]chlorido(4-methyl­phenyl­sulfon­yl-κS)palladium(II) dichloro­methane tris­olvate monohydrate
title_short [2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]chlorido(4-methyl­phenyl­sulfon­yl-κS)palladium(II) dichloro­methane tris­olvate monohydrate
title_sort [2,2′-bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) p,p′]chlorido(4-methyl­phenyl­sulfon­yl-κs)palladium(ii) dichloro­methane tris­olvate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238729/
https://www.ncbi.nlm.nih.gov/pubmed/22199606
http://dx.doi.org/10.1107/S1600536811049889
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