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[2,2′-Bis(diphenylphosphanyl)-1,1′-binaphthyl-κ(2) P,P′]chlorido(4-methylphenylsulfonyl-κS)palladium(II) dichloromethane trisolvate monohydrate
In the title compound, [Pd(C(7)H(7)O(2)S)Cl(C(44)H(32)P(2))]·3CH(2)Cl(2)·H(2)O, the geometry around the metal atom is distorted square planar, with a twist angle between the P—Pd—P and S—Pd—Cl planes of 28.11 (2)°. The two Pd—P bond lengths differ by about 0.04 Å and the biphosphane bite angle is sl...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238729/ https://www.ncbi.nlm.nih.gov/pubmed/22199606 http://dx.doi.org/10.1107/S1600536811049889 |
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author | Shrestha, Ruja Brennessel, William W. Weix, Daniel J. |
author_facet | Shrestha, Ruja Brennessel, William W. Weix, Daniel J. |
author_sort | Shrestha, Ruja |
collection | PubMed |
description | In the title compound, [Pd(C(7)H(7)O(2)S)Cl(C(44)H(32)P(2))]·3CH(2)Cl(2)·H(2)O, the geometry around the metal atom is distorted square planar, with a twist angle between the P—Pd—P and S—Pd—Cl planes of 28.11 (2)°. The two Pd—P bond lengths differ by about 0.04 Å and the biphosphane bite angle is slightly obtuse [92.92 (2)°]. There are three dichloromethane and one water molecule co-crystallized with the palladium molecule, all with atoms in general positions. Alternating water and palladium molecules form four-membered cyclic units through O—H⋯Cl and O—H⋯O hydrogen bonding. One of the dichloromethane solvent molecules is disordered over two positions in a 0.55:0.45 ratio. |
format | Online Article Text |
id | pubmed-3238729 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387292011-12-23 [2,2′-Bis(diphenylphosphanyl)-1,1′-binaphthyl-κ(2) P,P′]chlorido(4-methylphenylsulfonyl-κS)palladium(II) dichloromethane trisolvate monohydrate Shrestha, Ruja Brennessel, William W. Weix, Daniel J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(7)H(7)O(2)S)Cl(C(44)H(32)P(2))]·3CH(2)Cl(2)·H(2)O, the geometry around the metal atom is distorted square planar, with a twist angle between the P—Pd—P and S—Pd—Cl planes of 28.11 (2)°. The two Pd—P bond lengths differ by about 0.04 Å and the biphosphane bite angle is slightly obtuse [92.92 (2)°]. There are three dichloromethane and one water molecule co-crystallized with the palladium molecule, all with atoms in general positions. Alternating water and palladium molecules form four-membered cyclic units through O—H⋯Cl and O—H⋯O hydrogen bonding. One of the dichloromethane solvent molecules is disordered over two positions in a 0.55:0.45 ratio. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238729/ /pubmed/22199606 http://dx.doi.org/10.1107/S1600536811049889 Text en © Shrestha et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shrestha, Ruja Brennessel, William W. Weix, Daniel J. [2,2′-Bis(diphenylphosphanyl)-1,1′-binaphthyl-κ(2) P,P′]chlorido(4-methylphenylsulfonyl-κS)palladium(II) dichloromethane trisolvate monohydrate |
title | [2,2′-Bis(diphenylphosphanyl)-1,1′-binaphthyl-κ(2)
P,P′]chlorido(4-methylphenylsulfonyl-κS)palladium(II) dichloromethane trisolvate monohydrate |
title_full | [2,2′-Bis(diphenylphosphanyl)-1,1′-binaphthyl-κ(2)
P,P′]chlorido(4-methylphenylsulfonyl-κS)palladium(II) dichloromethane trisolvate monohydrate |
title_fullStr | [2,2′-Bis(diphenylphosphanyl)-1,1′-binaphthyl-κ(2)
P,P′]chlorido(4-methylphenylsulfonyl-κS)palladium(II) dichloromethane trisolvate monohydrate |
title_full_unstemmed | [2,2′-Bis(diphenylphosphanyl)-1,1′-binaphthyl-κ(2)
P,P′]chlorido(4-methylphenylsulfonyl-κS)palladium(II) dichloromethane trisolvate monohydrate |
title_short | [2,2′-Bis(diphenylphosphanyl)-1,1′-binaphthyl-κ(2)
P,P′]chlorido(4-methylphenylsulfonyl-κS)palladium(II) dichloromethane trisolvate monohydrate |
title_sort | [2,2′-bis(diphenylphosphanyl)-1,1′-binaphthyl-κ(2)
p,p′]chlorido(4-methylphenylsulfonyl-κs)palladium(ii) dichloromethane trisolvate monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238729/ https://www.ncbi.nlm.nih.gov/pubmed/22199606 http://dx.doi.org/10.1107/S1600536811049889 |
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