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(1,2,3,4-Tetrahydroisoquinoline-2-carbodithioato-κ(2) S,S′)(thiocyanato-κN)(triphenylphosphane)nickel(II)
The Ni(II) atom in the mononuclear title compound, [Ni(C(10)H(10)NS(2))(NCS)(C(18)H(15)P)], exists within a S(2)PN donor set that defines a distorted square-planar geometry. A significant asymmetry in the Ni—S bond lengths support the less effective trans effect of SCN(−) over PPh(3).
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238766/ https://www.ncbi.nlm.nih.gov/pubmed/22199643 http://dx.doi.org/10.1107/S1600536811050550 |