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(1,2,3,4-Tetrahydroisoquinoline-2-carbodithioato-κ(2) S,S′)(thiocyanato-κN)(triphenylphosphane)nickel(II)
The Ni(II) atom in the mononuclear title compound, [Ni(C(10)H(10)NS(2))(NCS)(C(18)H(15)P)], exists within a S(2)PN donor set that defines a distorted square-planar geometry. A significant asymmetry in the Ni—S bond lengths support the less effective trans effect of SCN(−) over PPh(3).
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238766/ https://www.ncbi.nlm.nih.gov/pubmed/22199643 http://dx.doi.org/10.1107/S1600536811050550 |
| _version_ | 1782219053691043840 |
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| author | Valarmathi, P. Thirumaran, S. Selvanayagam, S. |
| author_facet | Valarmathi, P. Thirumaran, S. Selvanayagam, S. |
| author_sort | Valarmathi, P. |
| collection | PubMed |
| description | The Ni(II) atom in the mononuclear title compound, [Ni(C(10)H(10)NS(2))(NCS)(C(18)H(15)P)], exists within a S(2)PN donor set that defines a distorted square-planar geometry. A significant asymmetry in the Ni—S bond lengths support the less effective trans effect of SCN(−) over PPh(3). |
| format | Online Article Text |
| id | pubmed-3238766 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32387662011-12-23 (1,2,3,4-Tetrahydroisoquinoline-2-carbodithioato-κ(2) S,S′)(thiocyanato-κN)(triphenylphosphane)nickel(II) Valarmathi, P. Thirumaran, S. Selvanayagam, S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni(II) atom in the mononuclear title compound, [Ni(C(10)H(10)NS(2))(NCS)(C(18)H(15)P)], exists within a S(2)PN donor set that defines a distorted square-planar geometry. A significant asymmetry in the Ni—S bond lengths support the less effective trans effect of SCN(−) over PPh(3). International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238766/ /pubmed/22199643 http://dx.doi.org/10.1107/S1600536811050550 Text en © Valarmathi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Valarmathi, P. Thirumaran, S. Selvanayagam, S. (1,2,3,4-Tetrahydroisoquinoline-2-carbodithioato-κ(2) S,S′)(thiocyanato-κN)(triphenylphosphane)nickel(II) |
| title | (1,2,3,4-Tetrahydroisoquinoline-2-carbodithioato-κ(2)
S,S′)(thiocyanato-κN)(triphenylphosphane)nickel(II) |
| title_full | (1,2,3,4-Tetrahydroisoquinoline-2-carbodithioato-κ(2)
S,S′)(thiocyanato-κN)(triphenylphosphane)nickel(II) |
| title_fullStr | (1,2,3,4-Tetrahydroisoquinoline-2-carbodithioato-κ(2)
S,S′)(thiocyanato-κN)(triphenylphosphane)nickel(II) |
| title_full_unstemmed | (1,2,3,4-Tetrahydroisoquinoline-2-carbodithioato-κ(2)
S,S′)(thiocyanato-κN)(triphenylphosphane)nickel(II) |
| title_short | (1,2,3,4-Tetrahydroisoquinoline-2-carbodithioato-κ(2)
S,S′)(thiocyanato-κN)(triphenylphosphane)nickel(II) |
| title_sort | (1,2,3,4-tetrahydroisoquinoline-2-carbodithioato-κ(2)
s,s′)(thiocyanato-κn)(triphenylphosphane)nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238766/ https://www.ncbi.nlm.nih.gov/pubmed/22199643 http://dx.doi.org/10.1107/S1600536811050550 |
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