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(1,2,3,4-Tetrahydroisoquinoline-2-carbodithioato-κ(2) S,S′)(thiocyanato-κN)(triphenylphosphane)nickel(II)

The Ni(II) atom in the mononuclear title compound, [Ni(C(10)H(10)NS(2))(NCS)(C(18)H(15)P)], exists within a S(2)PN donor set that defines a distorted square-planar geometry. A significant asymmetry in the Ni—S bond lengths support the less effective trans effect of SCN(−) over PPh(3).

Detalles Bibliográficos
Autores principales:	Valarmathi, P., Thirumaran, S., Selvanayagam, S.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2011
Materias:	Metal-Organic Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238766/ https://www.ncbi.nlm.nih.gov/pubmed/22199643 http://dx.doi.org/10.1107/S1600536811050550

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