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μ-Propane-1,3-dithiolato-κ(4) S,S′:S,S′-bis[dicarbonyl(triphenylphosphane-κP)iron(II)](Fe—Fe)
The title compound, [Fe(2)(C(3)H(6)S(2))(C(18)H(15)P)(2)(CO)(4)], which might serve as an active-site model of [FeFe]-hydrogenase, contains two fused Fe/S/C/C/C/S six-membered rings, one of which has a chair conformation and the other a boat conformation. Each Fe atom is coordinated by two carbonyl...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246933/ https://www.ncbi.nlm.nih.gov/pubmed/22219753 http://dx.doi.org/10.1107/S1600536811040621 |