μ-Propane-1,3-dithiol­ato-κ(4) S,S′:S,S′-bis­[dicarbon­yl(triphenyl­phosphane-κP)iron(II)](Fe—Fe)

The title compound, [Fe(2)(C(3)H(6)S(2))(C(18)H(15)P)(2)(CO)(4)], which might serve as an active-site model of [FeFe]-hydrogenase, contains two fused Fe/S/C/C/C/S six-membered rings, one of which has a chair conformation and the other a boat conformation. Each Fe atom is coordinated by two carbonyl...

Descripción completa

Detalles Bibliográficos
Autores principales: Yin, Bang-Shao, Li, Tian-Bao, Yang, Ming-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246933/
https://www.ncbi.nlm.nih.gov/pubmed/22219753
http://dx.doi.org/10.1107/S1600536811040621
Descripción
Sumario:The title compound, [Fe(2)(C(3)H(6)S(2))(C(18)H(15)P)(2)(CO)(4)], which might serve as an active-site model of [FeFe]-hydrogenase, contains two fused Fe/S/C/C/C/S six-membered rings, one of which has a chair conformation and the other a boat conformation. Each Fe atom is coordinated by two carbonyl ligands, a triphenyl­phosphane ligand and a bis-bidentate dithiol­ate ligand, and also forms an Fe—Fe bond [2.5167 (16) Å]. Together, the six bonded atoms form a very distorted octa­hedral arrangement.

Ejemplares similares