μ-Propane-1,3-dithiol­ato-κ(4) S,S′:S,S′-bis­[dicarbon­yl(triphenyl­phosphane-κP)iron(II)](Fe—Fe)

The title compound, [Fe(2)(C(3)H(6)S(2))(C(18)H(15)P)(2)(CO)(4)], which might serve as an active-site model of [FeFe]-hydrogenase, contains two fused Fe/S/C/C/C/S six-membered rings, one of which has a chair conformation and the other a boat conformation. Each Fe atom is coordinated by two carbonyl...

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Detalles Bibliográficos
Autores principales: Yin, Bang-Shao, Li, Tian-Bao, Yang, Ming-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246933/
https://www.ncbi.nlm.nih.gov/pubmed/22219753
http://dx.doi.org/10.1107/S1600536811040621
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author Yin, Bang-Shao
Li, Tian-Bao
Yang, Ming-Sheng
author_facet Yin, Bang-Shao
Li, Tian-Bao
Yang, Ming-Sheng
author_sort Yin, Bang-Shao
collection PubMed
description The title compound, [Fe(2)(C(3)H(6)S(2))(C(18)H(15)P)(2)(CO)(4)], which might serve as an active-site model of [FeFe]-hydrogenase, contains two fused Fe/S/C/C/C/S six-membered rings, one of which has a chair conformation and the other a boat conformation. Each Fe atom is coordinated by two carbonyl ligands, a triphenyl­phosphane ligand and a bis-bidentate dithiol­ate ligand, and also forms an Fe—Fe bond [2.5167 (16) Å]. Together, the six bonded atoms form a very distorted octa­hedral arrangement.
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spelling pubmed-32469332012-01-04 μ-Propane-1,3-dithiol­ato-κ(4) S,S′:S,S′-bis­[dicarbon­yl(triphenyl­phosphane-κP)iron(II)](Fe—Fe) Yin, Bang-Shao Li, Tian-Bao Yang, Ming-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(2)(C(3)H(6)S(2))(C(18)H(15)P)(2)(CO)(4)], which might serve as an active-site model of [FeFe]-hydrogenase, contains two fused Fe/S/C/C/C/S six-membered rings, one of which has a chair conformation and the other a boat conformation. Each Fe atom is coordinated by two carbonyl ligands, a triphenyl­phosphane ligand and a bis-bidentate dithiol­ate ligand, and also forms an Fe—Fe bond [2.5167 (16) Å]. Together, the six bonded atoms form a very distorted octa­hedral arrangement. International Union of Crystallography 2011-10-08 /pmc/articles/PMC3246933/ /pubmed/22219753 http://dx.doi.org/10.1107/S1600536811040621 Text en © Yin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yin, Bang-Shao
Li, Tian-Bao
Yang, Ming-Sheng
μ-Propane-1,3-dithiol­ato-κ(4) S,S′:S,S′-bis­[dicarbon­yl(triphenyl­phosphane-κP)iron(II)](Fe—Fe)
title μ-Propane-1,3-dithiol­ato-κ(4) S,S′:S,S′-bis­[dicarbon­yl(triphenyl­phosphane-κP)iron(II)](Fe—Fe)
title_full μ-Propane-1,3-dithiol­ato-κ(4) S,S′:S,S′-bis­[dicarbon­yl(triphenyl­phosphane-κP)iron(II)](Fe—Fe)
title_fullStr μ-Propane-1,3-dithiol­ato-κ(4) S,S′:S,S′-bis­[dicarbon­yl(triphenyl­phosphane-κP)iron(II)](Fe—Fe)
title_full_unstemmed μ-Propane-1,3-dithiol­ato-κ(4) S,S′:S,S′-bis­[dicarbon­yl(triphenyl­phosphane-κP)iron(II)](Fe—Fe)
title_short μ-Propane-1,3-dithiol­ato-κ(4) S,S′:S,S′-bis­[dicarbon­yl(triphenyl­phosphane-κP)iron(II)](Fe—Fe)
title_sort μ-propane-1,3-dithiol­ato-κ(4) s,s′:s,s′-bis­[dicarbon­yl(triphenyl­phosphane-κp)iron(ii)](fe—fe)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246933/
https://www.ncbi.nlm.nih.gov/pubmed/22219753
http://dx.doi.org/10.1107/S1600536811040621
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AT yangmingsheng mpropane13dithiolatok4ssssbisdicarbonyltriphenylphosphanekpironiifefe

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