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μ(4)-Orthothiocarbonato-tetrakis[tricarbonyliron(I)](2 Fe—Fe)
The fused bis-butterfly-shaped title compound, [Fe(4)(CS(4))(CO)(12)], possesses an orthothiocarbonate (CS(4) (4−)) ligand that acts as a bridge between two Fe(2)(CO)(6) units. A short intramolecular S⋯S contact [2.6984 (8) and 2.6977 (8) Å] occurs in each S(2)Fe(2)(CO)(6) fragment.
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246959/ https://www.ncbi.nlm.nih.gov/pubmed/22219779 http://dx.doi.org/10.1107/S1600536811041936 |