μ(4)-Orthothio­carbonato-tetra­kis­[tri­carbonyl­iron(I)](2 Fe—Fe)

The fused bis-butterfly-shaped title compound, [Fe(4)(CS(4))(CO)(12)], possesses an orthothio­carbonate (CS(4) (4−)) ligand that acts as a bridge between two Fe(2)(CO)(6) units. A short intra­molecular S⋯S contact [2.6984 (8) and 2.6977 (8) Å] occurs in each S(2)Fe(2)(CO)(6) fragment.

Detalles Bibliográficos
Autores principales: Shi, Yao-Cheng, Cheng, Huan-Ren, Yuan, Li-Min, Li, Qian-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246959/
https://www.ncbi.nlm.nih.gov/pubmed/22219779
http://dx.doi.org/10.1107/S1600536811041936
Descripción
Sumario:The fused bis-butterfly-shaped title compound, [Fe(4)(CS(4))(CO)(12)], possesses an orthothio­carbonate (CS(4) (4−)) ligand that acts as a bridge between two Fe(2)(CO)(6) units. A short intra­molecular S⋯S contact [2.6984 (8) and 2.6977 (8) Å] occurs in each S(2)Fe(2)(CO)(6) fragment.

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