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μ(4)-Orthothiocarbonato-tetrakis[tricarbonyliron(I)](2 Fe—Fe)
The fused bis-butterfly-shaped title compound, [Fe(4)(CS(4))(CO)(12)], possesses an orthothiocarbonate (CS(4) (4−)) ligand that acts as a bridge between two Fe(2)(CO)(6) units. A short intramolecular S⋯S contact [2.6984 (8) and 2.6977 (8) Å] occurs in each S(2)Fe(2)(CO)(6) fragment.
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246959/ https://www.ncbi.nlm.nih.gov/pubmed/22219779 http://dx.doi.org/10.1107/S1600536811041936 |
| _version_ | 1782220013358284800 |
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| author | Shi, Yao-Cheng Cheng, Huan-Ren Yuan, Li-Min Li, Qian-Kun |
| author_facet | Shi, Yao-Cheng Cheng, Huan-Ren Yuan, Li-Min Li, Qian-Kun |
| author_sort | Shi, Yao-Cheng |
| collection | PubMed |
| description | The fused bis-butterfly-shaped title compound, [Fe(4)(CS(4))(CO)(12)], possesses an orthothiocarbonate (CS(4) (4−)) ligand that acts as a bridge between two Fe(2)(CO)(6) units. A short intramolecular S⋯S contact [2.6984 (8) and 2.6977 (8) Å] occurs in each S(2)Fe(2)(CO)(6) fragment. |
| format | Online Article Text |
| id | pubmed-3246959 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32469592012-01-04 μ(4)-Orthothiocarbonato-tetrakis[tricarbonyliron(I)](2 Fe—Fe) Shi, Yao-Cheng Cheng, Huan-Ren Yuan, Li-Min Li, Qian-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The fused bis-butterfly-shaped title compound, [Fe(4)(CS(4))(CO)(12)], possesses an orthothiocarbonate (CS(4) (4−)) ligand that acts as a bridge between two Fe(2)(CO)(6) units. A short intramolecular S⋯S contact [2.6984 (8) and 2.6977 (8) Å] occurs in each S(2)Fe(2)(CO)(6) fragment. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3246959/ /pubmed/22219779 http://dx.doi.org/10.1107/S1600536811041936 Text en © Shi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shi, Yao-Cheng Cheng, Huan-Ren Yuan, Li-Min Li, Qian-Kun μ(4)-Orthothiocarbonato-tetrakis[tricarbonyliron(I)](2 Fe—Fe) |
| title | μ(4)-Orthothiocarbonato-tetrakis[tricarbonyliron(I)](2 Fe—Fe) |
| title_full | μ(4)-Orthothiocarbonato-tetrakis[tricarbonyliron(I)](2 Fe—Fe) |
| title_fullStr | μ(4)-Orthothiocarbonato-tetrakis[tricarbonyliron(I)](2 Fe—Fe) |
| title_full_unstemmed | μ(4)-Orthothiocarbonato-tetrakis[tricarbonyliron(I)](2 Fe—Fe) |
| title_short | μ(4)-Orthothiocarbonato-tetrakis[tricarbonyliron(I)](2 Fe—Fe) |
| title_sort | μ(4)-orthothiocarbonato-tetrakis[tricarbonyliron(i)](2 fe—fe) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246959/ https://www.ncbi.nlm.nih.gov/pubmed/22219779 http://dx.doi.org/10.1107/S1600536811041936 |
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