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Penta­carbonyl-1κ(2) C,2κ(3) C-[(diphenyl­phosphor­yl)diphenyl­phosphane-1κP]-μ-ethane-1,2-dithiol­ato-1:2κ(4) S,S′:S,S′-diiron(I)(Fe—Fe)

The dinuclear title compound, [Fe(2)(C(2)H(4)S(2))(C(24)H(20)OP(2))(CO)(5)] or (μ-SCH(2)CH(2)S-μ)Fe(2)(CO)(5)[Ph(2)PP(O)Ph(2)], con­tains a butterfly-shaped Fe(2)S(2) core in which the Fe⋯Fe separation is 2.5275 (6) Å. One of the Fe atoms is also coordinated to three carbonyl ligands and the other t...

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Detalles Bibliográficos
Autores principales: Liu, Xu-Feng, Yu, Xiao-Yong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246973/
https://www.ncbi.nlm.nih.gov/pubmed/22219793
http://dx.doi.org/10.1107/S1600536811042139