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Pentacarbonyl-1κ(2) C,2κ(3) C-[(diphenylphosphoryl)diphenylphosphane-1κP]-μ-ethane-1,2-dithiolato-1:2κ(4) S,S′:S,S′-diiron(I)(Fe—Fe)
The dinuclear title compound, [Fe(2)(C(2)H(4)S(2))(C(24)H(20)OP(2))(CO)(5)] or (μ-SCH(2)CH(2)S-μ)Fe(2)(CO)(5)[Ph(2)PP(O)Ph(2)], contains a butterfly-shaped Fe(2)S(2) core in which the Fe⋯Fe separation is 2.5275 (6) Å. One of the Fe atoms is also coordinated to three carbonyl ligands and the other t...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246973/ https://www.ncbi.nlm.nih.gov/pubmed/22219793 http://dx.doi.org/10.1107/S1600536811042139 |
| _version_ | 1782220016758816768 |
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| author | Liu, Xu-Feng Yu, Xiao-Yong |
| author_facet | Liu, Xu-Feng Yu, Xiao-Yong |
| author_sort | Liu, Xu-Feng |
| collection | PubMed |
| description | The dinuclear title compound, [Fe(2)(C(2)H(4)S(2))(C(24)H(20)OP(2))(CO)(5)] or (μ-SCH(2)CH(2)S-μ)Fe(2)(CO)(5)[Ph(2)PP(O)Ph(2)], contains a butterfly-shaped Fe(2)S(2) core in which the Fe⋯Fe separation is 2.5275 (6) Å. One of the Fe atoms is also coordinated to three carbonyl ligands and the other to two carbonyl ligands and one phosphane ligand [Ph(2)PP(O)Ph(2)]. Both Fe-atom geometries could be described as grossly distorted octahedral and the Ph(2)PP(O)Ph(2) ligand lies trans to the Fe⋯Fe link. |
| format | Online Article Text |
| id | pubmed-3246973 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32469732012-01-04 Pentacarbonyl-1κ(2) C,2κ(3) C-[(diphenylphosphoryl)diphenylphosphane-1κP]-μ-ethane-1,2-dithiolato-1:2κ(4) S,S′:S,S′-diiron(I)(Fe—Fe) Liu, Xu-Feng Yu, Xiao-Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title compound, [Fe(2)(C(2)H(4)S(2))(C(24)H(20)OP(2))(CO)(5)] or (μ-SCH(2)CH(2)S-μ)Fe(2)(CO)(5)[Ph(2)PP(O)Ph(2)], contains a butterfly-shaped Fe(2)S(2) core in which the Fe⋯Fe separation is 2.5275 (6) Å. One of the Fe atoms is also coordinated to three carbonyl ligands and the other to two carbonyl ligands and one phosphane ligand [Ph(2)PP(O)Ph(2)]. Both Fe-atom geometries could be described as grossly distorted octahedral and the Ph(2)PP(O)Ph(2) ligand lies trans to the Fe⋯Fe link. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246973/ /pubmed/22219793 http://dx.doi.org/10.1107/S1600536811042139 Text en © Liu and Yu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Xu-Feng Yu, Xiao-Yong Pentacarbonyl-1κ(2) C,2κ(3) C-[(diphenylphosphoryl)diphenylphosphane-1κP]-μ-ethane-1,2-dithiolato-1:2κ(4) S,S′:S,S′-diiron(I)(Fe—Fe) |
| title | Pentacarbonyl-1κ(2)
C,2κ(3)
C-[(diphenylphosphoryl)diphenylphosphane-1κP]-μ-ethane-1,2-dithiolato-1:2κ(4)
S,S′:S,S′-diiron(I)(Fe—Fe) |
| title_full | Pentacarbonyl-1κ(2)
C,2κ(3)
C-[(diphenylphosphoryl)diphenylphosphane-1κP]-μ-ethane-1,2-dithiolato-1:2κ(4)
S,S′:S,S′-diiron(I)(Fe—Fe) |
| title_fullStr | Pentacarbonyl-1κ(2)
C,2κ(3)
C-[(diphenylphosphoryl)diphenylphosphane-1κP]-μ-ethane-1,2-dithiolato-1:2κ(4)
S,S′:S,S′-diiron(I)(Fe—Fe) |
| title_full_unstemmed | Pentacarbonyl-1κ(2)
C,2κ(3)
C-[(diphenylphosphoryl)diphenylphosphane-1κP]-μ-ethane-1,2-dithiolato-1:2κ(4)
S,S′:S,S′-diiron(I)(Fe—Fe) |
| title_short | Pentacarbonyl-1κ(2)
C,2κ(3)
C-[(diphenylphosphoryl)diphenylphosphane-1κP]-μ-ethane-1,2-dithiolato-1:2κ(4)
S,S′:S,S′-diiron(I)(Fe—Fe) |
| title_sort | pentacarbonyl-1κ(2)
c,2κ(3)
c-[(diphenylphosphoryl)diphenylphosphane-1κp]-μ-ethane-1,2-dithiolato-1:2κ(4)
s,s′:s,s′-diiron(i)(fe—fe) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246973/ https://www.ncbi.nlm.nih.gov/pubmed/22219793 http://dx.doi.org/10.1107/S1600536811042139 |
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