5-[2-(4-Acetyl­oxyphen­yl)ethen­yl]benzene-1,3-diyl diacetate

The title compound, C(20)H(18)O(6), was prepared from resveratrol {systematic name: 5-[(E)-2-(4-hy­droxy­phen­yl)ethen­yl]ben­z­ene-1,3-diol}, which can be isolated from grapes, through triacetyl­ation with using acetic anhydride in pyridine. The two benzene rings are approximately coplanar, making...

Descripción completa

Detalles Bibliográficos
Autores principales: Tang, Lin, Dai, Dongmei, Gong, Yanqing, Zhong, Jialiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247513/
https://www.ncbi.nlm.nih.gov/pubmed/22220131
http://dx.doi.org/10.1107/S1600536811044722
_version_ 1782220124429746176
author Tang, Lin
Dai, Dongmei
Gong, Yanqing
Zhong, Jialiang
author_facet Tang, Lin
Dai, Dongmei
Gong, Yanqing
Zhong, Jialiang
author_sort Tang, Lin
collection PubMed
description The title compound, C(20)H(18)O(6), was prepared from resveratrol {systematic name: 5-[(E)-2-(4-hy­droxy­phen­yl)ethen­yl]ben­z­ene-1,3-diol}, which can be isolated from grapes, through triacetyl­ation with using acetic anhydride in pyridine. The two benzene rings are approximately coplanar, making a dihedral angle of 6.64 (14)°, and the three acet­oxy group are located on the same side of the plane. The skeleton of the compound resembles a table with three legs. In the crystal, mol­ecules are linked via C—H⋯O interactions, forming inversion dimers. These dimers are further linked via C—H⋯O interactions, forming a three-dimensional structure.
format Online
Article
Text
id pubmed-3247513
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32475132012-01-04 5-[2-(4-Acetyl­oxyphen­yl)ethen­yl]benzene-1,3-diyl diacetate Tang, Lin Dai, Dongmei Gong, Yanqing Zhong, Jialiang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(18)O(6), was prepared from resveratrol {systematic name: 5-[(E)-2-(4-hy­droxy­phen­yl)ethen­yl]ben­z­ene-1,3-diol}, which can be isolated from grapes, through triacetyl­ation with using acetic anhydride in pyridine. The two benzene rings are approximately coplanar, making a dihedral angle of 6.64 (14)°, and the three acet­oxy group are located on the same side of the plane. The skeleton of the compound resembles a table with three legs. In the crystal, mol­ecules are linked via C—H⋯O interactions, forming inversion dimers. These dimers are further linked via C—H⋯O interactions, forming a three-dimensional structure. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247513/ /pubmed/22220131 http://dx.doi.org/10.1107/S1600536811044722 Text en © Tang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tang, Lin
Dai, Dongmei
Gong, Yanqing
Zhong, Jialiang
5-[2-(4-Acetyl­oxyphen­yl)ethen­yl]benzene-1,3-diyl diacetate
title 5-[2-(4-Acetyl­oxyphen­yl)ethen­yl]benzene-1,3-diyl diacetate
title_full 5-[2-(4-Acetyl­oxyphen­yl)ethen­yl]benzene-1,3-diyl diacetate
title_fullStr 5-[2-(4-Acetyl­oxyphen­yl)ethen­yl]benzene-1,3-diyl diacetate
title_full_unstemmed 5-[2-(4-Acetyl­oxyphen­yl)ethen­yl]benzene-1,3-diyl diacetate
title_short 5-[2-(4-Acetyl­oxyphen­yl)ethen­yl]benzene-1,3-diyl diacetate
title_sort 5-[2-(4-acetyl­oxyphen­yl)ethen­yl]benzene-1,3-diyl diacetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247513/
https://www.ncbi.nlm.nih.gov/pubmed/22220131
http://dx.doi.org/10.1107/S1600536811044722
work_keys_str_mv AT tanglin 524acetyloxyphenylethenylbenzene13diyldiacetate
AT daidongmei 524acetyloxyphenylethenylbenzene13diyldiacetate
AT gongyanqing 524acetyloxyphenylethenylbenzene13diyldiacetate
AT zhongjialiang 524acetyloxyphenylethenylbenzene13diyldiacetate

Ejemplares similares