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Synthesis of fluoranthenes by hydroarylation of alkynes catalyzed by gold(I) or gallium trichloride

Electrophilic gold(I) catalyst 6 competes with GaCl(3) as the catalyst of choice in the synthesis of fluoranthenes by intramolecular hydroarylation of alkynes. The potential of this catalyst for the preparation of polyarenes is illustrated by a synthesis of two functionalized decacyclenes in a one-p...

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Detalles Bibliográficos
Autores principales: Pascual, Sergio, Bour, Christophe, de Mendoza, Paula, Echavarren, Antonio M
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3252853/
https://www.ncbi.nlm.nih.gov/pubmed/22238527
http://dx.doi.org/10.3762/bjoc.7.178