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Synthesis of fluoranthenes by hydroarylation of alkynes catalyzed by gold(I) or gallium trichloride
Electrophilic gold(I) catalyst 6 competes with GaCl(3) as the catalyst of choice in the synthesis of fluoranthenes by intramolecular hydroarylation of alkynes. The potential of this catalyst for the preparation of polyarenes is illustrated by a synthesis of two functionalized decacyclenes in a one-p...
Autores principales: | Pascual, Sergio, Bour, Christophe, de Mendoza, Paula, Echavarren, Antonio M |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3252853/ https://www.ncbi.nlm.nih.gov/pubmed/22238527 http://dx.doi.org/10.3762/bjoc.7.178 |
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