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Valence isomerization of cyclohepta-1,3,5-triene and its heteroelement analogues

The valence isomerization of the all-carbon and heteroelement analogues of cyclohepta-1,3,5-triene into the corresponding bicyclo[4.1.0]hepta-2,4-dienes is reviewed to show the impact of the heteroatom on the stability of both valence isomers. The focus is on the parent systems and their synthetic a...

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Detalles Bibliográficos
Autores principales: Jansen, Helen, Slootweg, J Chris, Lammertsma, Koop
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3252876/
https://www.ncbi.nlm.nih.gov/pubmed/22238550
http://dx.doi.org/10.3762/bjoc.7.201