Valence isomerization of cyclohepta-1,3,5-triene and its heteroelement analogues

The valence isomerization of the all-carbon and heteroelement analogues of cyclohepta-1,3,5-triene into the corresponding bicyclo[4.1.0]hepta-2,4-dienes is reviewed to show the impact of the heteroatom on the stability of both valence isomers. The focus is on the parent systems and their synthetic a...

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Autores principales: Jansen, Helen, Slootweg, J Chris, Lammertsma, Koop
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3252876/
https://www.ncbi.nlm.nih.gov/pubmed/22238550
http://dx.doi.org/10.3762/bjoc.7.201
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author Jansen, Helen
Slootweg, J Chris
Lammertsma, Koop
author_facet Jansen, Helen
Slootweg, J Chris
Lammertsma, Koop
author_sort Jansen, Helen
collection PubMed
description The valence isomerization of the all-carbon and heteroelement analogues of cyclohepta-1,3,5-triene into the corresponding bicyclo[4.1.0]hepta-2,4-dienes is reviewed to show the impact of the heteroatom on the stability of both valence isomers. The focus is on the parent systems and their synthetic applications.
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spelling pubmed-32528762012-01-11 Valence isomerization of cyclohepta-1,3,5-triene and its heteroelement analogues Jansen, Helen Slootweg, J Chris Lammertsma, Koop Beilstein J Org Chem Review The valence isomerization of the all-carbon and heteroelement analogues of cyclohepta-1,3,5-triene into the corresponding bicyclo[4.1.0]hepta-2,4-dienes is reviewed to show the impact of the heteroatom on the stability of both valence isomers. The focus is on the parent systems and their synthetic applications. Beilstein-Institut 2011-12-21 /pmc/articles/PMC3252876/ /pubmed/22238550 http://dx.doi.org/10.3762/bjoc.7.201 Text en Copyright © 2011, Jansen et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Review
Jansen, Helen
Slootweg, J Chris
Lammertsma, Koop
Valence isomerization of cyclohepta-1,3,5-triene and its heteroelement analogues
title Valence isomerization of cyclohepta-1,3,5-triene and its heteroelement analogues
title_full Valence isomerization of cyclohepta-1,3,5-triene and its heteroelement analogues
title_fullStr Valence isomerization of cyclohepta-1,3,5-triene and its heteroelement analogues
title_full_unstemmed Valence isomerization of cyclohepta-1,3,5-triene and its heteroelement analogues
title_short Valence isomerization of cyclohepta-1,3,5-triene and its heteroelement analogues
title_sort valence isomerization of cyclohepta-1,3,5-triene and its heteroelement analogues
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3252876/
https://www.ncbi.nlm.nih.gov/pubmed/22238550
http://dx.doi.org/10.3762/bjoc.7.201
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AT slootwegjchris valenceisomerizationofcyclohepta135trieneanditsheteroelementanalogues
AT lammertsmakoop valenceisomerizationofcyclohepta135trieneanditsheteroelementanalogues

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