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First microwave-assisted synthesis of an electron-rich phosphane and its coordination chemistry with platinum(II) and palladium(II)

The P–O ligand 3-(di(2-methoxyphenyl)phosphanyl)propionic acid (HL) was synthesized by a microwave-assisted reaction of a secondary phosphane. The coordination of HL to Pt(II) yielded the neutral mononuclear complex trans-[PtCl(κ(2)-P,O-L)(κ-P-HL)] (1), while the reaction of PdClMe(η(4)-COD) (COD = ...

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Detalles Bibliográficos
Autores principales: Trettenbrein, Barbara, Fessler, Markus, Ruggenthaler, Martin, Haringer, Stephan, Oberhuber, Dennis, Czermak, Georg, Brüggeller, Peter, Oberhauser, Werner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier Sequoia [etc.] 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3271353/
https://www.ncbi.nlm.nih.gov/pubmed/22310808
http://dx.doi.org/10.1016/j.ica.2011.05.020