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First microwave-assisted synthesis of an electron-rich phosphane and its coordination chemistry with platinum(II) and palladium(II)
The P–O ligand 3-(di(2-methoxyphenyl)phosphanyl)propionic acid (HL) was synthesized by a microwave-assisted reaction of a secondary phosphane. The coordination of HL to Pt(II) yielded the neutral mononuclear complex trans-[PtCl(κ(2)-P,O-L)(κ-P-HL)] (1), while the reaction of PdClMe(η(4)-COD) (COD = ...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier Sequoia [etc.]
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3271353/ https://www.ncbi.nlm.nih.gov/pubmed/22310808 http://dx.doi.org/10.1016/j.ica.2011.05.020 |
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author | Trettenbrein, Barbara Fessler, Markus Ruggenthaler, Martin Haringer, Stephan Oberhuber, Dennis Czermak, Georg Brüggeller, Peter Oberhauser, Werner |
author_facet | Trettenbrein, Barbara Fessler, Markus Ruggenthaler, Martin Haringer, Stephan Oberhuber, Dennis Czermak, Georg Brüggeller, Peter Oberhauser, Werner |
author_sort | Trettenbrein, Barbara |
collection | PubMed |
description | The P–O ligand 3-(di(2-methoxyphenyl)phosphanyl)propionic acid (HL) was synthesized by a microwave-assisted reaction of a secondary phosphane. The coordination of HL to Pt(II) yielded the neutral mononuclear complex trans-[PtCl(κ(2)-P,O-L)(κ-P-HL)] (1), while the reaction of PdClMe(η(4)-COD) (COD = 1,4-cyclooctadiene) with HL in the presence of NEt(3) gave the anionic Pd(II) compound of the formula (HNEt(3))[PdClMe(κ(2)-P,O-L)] (2). Upon crystallization of the latter compound the neutral chloride-bridged dimetallic compound cis-[Pd(μ-Cl)Me(HL)](2) (3) was obtained. HL, 1 and 3·CH(2)Cl(2) have been characterized by single crystal X-ray structure analyses. |
format | Online Article Text |
id | pubmed-3271353 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | Elsevier Sequoia [etc.] |
record_format | MEDLINE/PubMed |
spelling | pubmed-32713532012-02-03 First microwave-assisted synthesis of an electron-rich phosphane and its coordination chemistry with platinum(II) and palladium(II) Trettenbrein, Barbara Fessler, Markus Ruggenthaler, Martin Haringer, Stephan Oberhuber, Dennis Czermak, Georg Brüggeller, Peter Oberhauser, Werner Inorganica Chim Acta Note The P–O ligand 3-(di(2-methoxyphenyl)phosphanyl)propionic acid (HL) was synthesized by a microwave-assisted reaction of a secondary phosphane. The coordination of HL to Pt(II) yielded the neutral mononuclear complex trans-[PtCl(κ(2)-P,O-L)(κ-P-HL)] (1), while the reaction of PdClMe(η(4)-COD) (COD = 1,4-cyclooctadiene) with HL in the presence of NEt(3) gave the anionic Pd(II) compound of the formula (HNEt(3))[PdClMe(κ(2)-P,O-L)] (2). Upon crystallization of the latter compound the neutral chloride-bridged dimetallic compound cis-[Pd(μ-Cl)Me(HL)](2) (3) was obtained. HL, 1 and 3·CH(2)Cl(2) have been characterized by single crystal X-ray structure analyses. Elsevier Sequoia [etc.] 2011-09-01 /pmc/articles/PMC3271353/ /pubmed/22310808 http://dx.doi.org/10.1016/j.ica.2011.05.020 Text en © 2011 Elsevier B.V. https://creativecommons.org/licenses/by-nc-nd/3.0/ Open Access under CC BY-NC-ND 3.0 (https://creativecommons.org/licenses/by-nc-nd/3.0/) license |
spellingShingle | Note Trettenbrein, Barbara Fessler, Markus Ruggenthaler, Martin Haringer, Stephan Oberhuber, Dennis Czermak, Georg Brüggeller, Peter Oberhauser, Werner First microwave-assisted synthesis of an electron-rich phosphane and its coordination chemistry with platinum(II) and palladium(II) |
title | First microwave-assisted synthesis of an electron-rich phosphane and its coordination chemistry with platinum(II) and palladium(II) |
title_full | First microwave-assisted synthesis of an electron-rich phosphane and its coordination chemistry with platinum(II) and palladium(II) |
title_fullStr | First microwave-assisted synthesis of an electron-rich phosphane and its coordination chemistry with platinum(II) and palladium(II) |
title_full_unstemmed | First microwave-assisted synthesis of an electron-rich phosphane and its coordination chemistry with platinum(II) and palladium(II) |
title_short | First microwave-assisted synthesis of an electron-rich phosphane and its coordination chemistry with platinum(II) and palladium(II) |
title_sort | first microwave-assisted synthesis of an electron-rich phosphane and its coordination chemistry with platinum(ii) and palladium(ii) |
topic | Note |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3271353/ https://www.ncbi.nlm.nih.gov/pubmed/22310808 http://dx.doi.org/10.1016/j.ica.2011.05.020 |
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