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Synthesis of highly transparent ultrananocrystalline diamond films from a low-pressure, low-temperature focused microwave plasma jet
This paper describes a new low-temperature process underlying the synthesis of highly transparent ultrananocrystalline diamond [UNCD] films by low-pressure and unheated microwave plasma jet-enhanced chemical vapor deposition with Ar-1%CH(4)-10%H(2 )gas chemistry. The unique low-pressure/low-temperat...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3271979/ https://www.ncbi.nlm.nih.gov/pubmed/22260391 http://dx.doi.org/10.1186/1556-276X-7-82 |
Sumario: | This paper describes a new low-temperature process underlying the synthesis of highly transparent ultrananocrystalline diamond [UNCD] films by low-pressure and unheated microwave plasma jet-enhanced chemical vapor deposition with Ar-1%CH(4)-10%H(2 )gas chemistry. The unique low-pressure/low-temperature [LPLT] plasma jet-enhanced growth even with added H(2 )and unheated substrates yields UNCD films similar to those prepared by plasma-enhanced growth without addition of H(2 )and heating procedure. This is due to the focused plasma jet which effectively compensated for the sluggish kinetics associated with LPLT growth. The effects of pressure on UNCD film synthesis from the microwave plasma jet were systematically investigated. The results indicated that the substrate temperature, grain size, surface roughness, and sp(3 )carbon content in the films decreased with decreasing pressure. The reason is due to the great reduction of H(α )emission to lower the etching of sp(2 )carbon phase, resulting from the increase of mean free path with decreasing pressure. We have demonstrated that the transition from nanocrystalline (80 nm) to ultrananocrystalline (3 to 5 nm) diamond films grown via microwave Ar-1%CH(4)-10%H(2 )plasma jets could be controlled by changing the pressure from 100 to 30 Torr. The 250-nm-thick UNCD film was synthesized on glass substrates (glass transition temperature [T(g)] 557°C) using the unique LPLT (30 Torr/460°C) microwave plasma jet, which produced UNCD films with a high sp(3 )carbon content (95.65%) and offered high optical transmittance (approximately 86% at 700 nm). |
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