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Tetra­carbon­yl[bis­(diphenyl­phosphan­yl)tetra­methyl­disiloxane-κ(2) P,P′]chromium(0)

The title compound, [Cr(C(28)H(32)OP(2)Si(2))(CO)(4)], was obtained by the ligand-exchange reaction of Cr(CO)(6) with (Ph(2)PSiMe(2))(2)O in refluxing toluene. The CrC(4)P(2) coordination geometry is distorted octa­hedral, with a P—Cr—P bite angle of 99.22 (4)°.

Detalles Bibliográficos
Autores principales: Peulecke, Normen, Müller, Bernd H., Spannenberg, Anke, Rosenthal, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274860/
https://www.ncbi.nlm.nih.gov/pubmed/22346807
http://dx.doi.org/10.1107/S1600536812000219