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Tetracarbonyl[bis(diphenylphosphanyl)tetramethyldisiloxane-κ(2) P,P′]chromium(0)
The title compound, [Cr(C(28)H(32)OP(2)Si(2))(CO)(4)], was obtained by the ligand-exchange reaction of Cr(CO)(6) with (Ph(2)PSiMe(2))(2)O in refluxing toluene. The CrC(4)P(2) coordination geometry is distorted octahedral, with a P—Cr—P bite angle of 99.22 (4)°.
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274860/ https://www.ncbi.nlm.nih.gov/pubmed/22346807 http://dx.doi.org/10.1107/S1600536812000219 |