Tetra­carbon­yl[bis­(diphenyl­phosphan­yl)tetra­methyl­disiloxane-κ(2) P,P′]chromium(0)

The title compound, [Cr(C(28)H(32)OP(2)Si(2))(CO)(4)], was obtained by the ligand-exchange reaction of Cr(CO)(6) with (Ph(2)PSiMe(2))(2)O in refluxing toluene. The CrC(4)P(2) coordination geometry is distorted octa­hedral, with a P—Cr—P bite angle of 99.22 (4)°.

Detalles Bibliográficos
Autores principales: Peulecke, Normen, Müller, Bernd H., Spannenberg, Anke, Rosenthal, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274860/
https://www.ncbi.nlm.nih.gov/pubmed/22346807
http://dx.doi.org/10.1107/S1600536812000219
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author Peulecke, Normen
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_facet Peulecke, Normen
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_sort Peulecke, Normen
collection PubMed
description The title compound, [Cr(C(28)H(32)OP(2)Si(2))(CO)(4)], was obtained by the ligand-exchange reaction of Cr(CO)(6) with (Ph(2)PSiMe(2))(2)O in refluxing toluene. The CrC(4)P(2) coordination geometry is distorted octa­hedral, with a P—Cr—P bite angle of 99.22 (4)°.
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spelling pubmed-32748602012-02-15 Tetra­carbon­yl[bis­(diphenyl­phosphan­yl)tetra­methyl­disiloxane-κ(2) P,P′]chromium(0) Peulecke, Normen Müller, Bernd H. Spannenberg, Anke Rosenthal, Uwe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cr(C(28)H(32)OP(2)Si(2))(CO)(4)], was obtained by the ligand-exchange reaction of Cr(CO)(6) with (Ph(2)PSiMe(2))(2)O in refluxing toluene. The CrC(4)P(2) coordination geometry is distorted octa­hedral, with a P—Cr—P bite angle of 99.22 (4)°. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274860/ /pubmed/22346807 http://dx.doi.org/10.1107/S1600536812000219 Text en © Peulecke et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Peulecke, Normen
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
Tetra­carbon­yl[bis­(diphenyl­phosphan­yl)tetra­methyl­disiloxane-κ(2) P,P′]chromium(0)
title Tetra­carbon­yl[bis­(diphenyl­phosphan­yl)tetra­methyl­disiloxane-κ(2) P,P′]chromium(0)
title_full Tetra­carbon­yl[bis­(diphenyl­phosphan­yl)tetra­methyl­disiloxane-κ(2) P,P′]chromium(0)
title_fullStr Tetra­carbon­yl[bis­(diphenyl­phosphan­yl)tetra­methyl­disiloxane-κ(2) P,P′]chromium(0)
title_full_unstemmed Tetra­carbon­yl[bis­(diphenyl­phosphan­yl)tetra­methyl­disiloxane-κ(2) P,P′]chromium(0)
title_short Tetra­carbon­yl[bis­(diphenyl­phosphan­yl)tetra­methyl­disiloxane-κ(2) P,P′]chromium(0)
title_sort tetra­carbon­yl[bis­(diphenyl­phosphan­yl)tetra­methyl­disiloxane-κ(2) p,p′]chromium(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274860/
https://www.ncbi.nlm.nih.gov/pubmed/22346807
http://dx.doi.org/10.1107/S1600536812000219
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