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Effect of the Leaving Group and Solvent Combination on the LFER Reaction Constants

Fine effects that influence the variations of the reaction constants s(f) in LFER log k = s(f)(N(f) + E(f)) have been summarized here. Increasing solvent polarity in the series of binary mixtures increases the solvolysis rates for the same factor for all benzhydryl derivatives in which the solvation...

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Detalles Bibliográficos
Autores principales: Matić, Mirela, Jurić, Sandra, Denegri, Bernard, Kronja, Olga
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3292003/
https://www.ncbi.nlm.nih.gov/pubmed/22408434
http://dx.doi.org/10.3390/ijms13022012