Cargando…
Effect of the Leaving Group and Solvent Combination on the LFER Reaction Constants
Fine effects that influence the variations of the reaction constants s(f) in LFER log k = s(f)(N(f) + E(f)) have been summarized here. Increasing solvent polarity in the series of binary mixtures increases the solvolysis rates for the same factor for all benzhydryl derivatives in which the solvation...
Autores principales: | Matić, Mirela, Jurić, Sandra, Denegri, Bernard, Kronja, Olga |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Molecular Diversity Preservation International (MDPI)
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3292003/ https://www.ncbi.nlm.nih.gov/pubmed/22408434 http://dx.doi.org/10.3390/ijms13022012 |
Ejemplares similares
-
Extended Grunwald-Winstein Analysis - LFER Used to Gauge Solvent Effects in p-Nitrophenyl Chloroformate Solvolysis
por: D’Souza, Malcolm J., et al.
Publicado: (2008) -
LFER Studies Evaluating Solvent Effects on an α-Chloro-and two β,β,β-Trichloro-Ethyl Chloroformate Esters
por: D’Souza, Malcolm J., et al.
Publicado: (2014) -
Use of Linear Free Energy Relationships (LFERs) to Elucidate the Mechanisms of Reaction of a γ-Methyl-β-alkynyl and an ortho-Substituted Aryl Chloroformate Ester
por: D’Souza, Malcolm J., et al.
Publicado: (2012) -
Solvent-dependent conductance decay constants in single cluster junctions
por: Choi, Bonnie, et al.
Publicado: (2016) -
Constant
pH Molecular Dynamics in Explicit Solvent
with Enveloping Distribution Sampling and Hamiltonian Exchange
por: Lee, Juyong, et al.
Publicado: (2014)