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(+)-Chlorido[(1,2,3,4-η;κP (2′))-2′-diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate
In the title complex, [RhCl(C(44)H(32)OP(2))]·CH(3)OH, the Rh(I) ion is coordinated by a naphthyl group of a partially oxidized 2,2′-bis(diphenylphosphanyl)-1,1′-binaphthyl (BINAP) ligand in a η(4) mode, one P atom of the diphenylphosphanyl group and one Cl atom. The P=O group does not interact...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297224/ https://www.ncbi.nlm.nih.gov/pubmed/22412414 http://dx.doi.org/10.1107/S1600536812003418 |