(+)-Chlorido[(1,2,3,4-η;κP (2′))-2′-diphenyl­phosphanyl-2-diphenyl­phosphoryl-1,1′-binaphth­yl]rhodium(I) methanol monosolvate

In the title complex, [RhCl(C(44)H(32)OP(2))]·CH(3)OH, the Rh(I) ion is coordinated by a naphthyl group of a partially oxidized 2,2′-bis­(diphenyl­phosphan­yl)-1,1′-binaphthyl (BINAP) ligand in a η(4) mode, one P atom of the diphenyl­phosphanyl group and one Cl atom. The P=O group does not inter­act...

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Detalles Bibliográficos
Autores principales: Meissner, Antje, Selle, Carmen, Drexler, Hans-Joachim, Heller, Detlef
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297224/
https://www.ncbi.nlm.nih.gov/pubmed/22412414
http://dx.doi.org/10.1107/S1600536812003418
Descripción
Sumario:In the title complex, [RhCl(C(44)H(32)OP(2))]·CH(3)OH, the Rh(I) ion is coordinated by a naphthyl group of a partially oxidized 2,2′-bis­(diphenyl­phosphan­yl)-1,1′-binaphthyl (BINAP) ligand in a η(4) mode, one P atom of the diphenyl­phosphanyl group and one Cl atom. The P=O group does not inter­act with the Rh(I) ion but accepts an O—H⋯O hydrogen bond from the methanol solvent mol­ecule.

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