(+)-Chlorido[(1,2,3,4-η;κP (2′))-2′-diphenyl­phosphanyl-2-diphenyl­phosphoryl-1,1′-binaphth­yl]rhodium(I) methanol monosolvate

In the title complex, [RhCl(C(44)H(32)OP(2))]·CH(3)OH, the Rh(I) ion is coordinated by a naphthyl group of a partially oxidized 2,2′-bis­(diphenyl­phosphan­yl)-1,1′-binaphthyl (BINAP) ligand in a η(4) mode, one P atom of the diphenyl­phosphanyl group and one Cl atom. The P=O group does not inter­act...

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Detalles Bibliográficos
Autores principales: Meissner, Antje, Selle, Carmen, Drexler, Hans-Joachim, Heller, Detlef
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297224/
https://www.ncbi.nlm.nih.gov/pubmed/22412414
http://dx.doi.org/10.1107/S1600536812003418
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author Meissner, Antje
Selle, Carmen
Drexler, Hans-Joachim
Heller, Detlef
author_facet Meissner, Antje
Selle, Carmen
Drexler, Hans-Joachim
Heller, Detlef
author_sort Meissner, Antje
collection PubMed
description In the title complex, [RhCl(C(44)H(32)OP(2))]·CH(3)OH, the Rh(I) ion is coordinated by a naphthyl group of a partially oxidized 2,2′-bis­(diphenyl­phosphan­yl)-1,1′-binaphthyl (BINAP) ligand in a η(4) mode, one P atom of the diphenyl­phosphanyl group and one Cl atom. The P=O group does not inter­act with the Rh(I) ion but accepts an O—H⋯O hydrogen bond from the methanol solvent mol­ecule.
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spelling pubmed-32972242012-03-12 (+)-Chlorido[(1,2,3,4-η;κP (2′))-2′-diphenyl­phosphanyl-2-diphenyl­phosphoryl-1,1′-binaphth­yl]rhodium(I) methanol monosolvate Meissner, Antje Selle, Carmen Drexler, Hans-Joachim Heller, Detlef Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [RhCl(C(44)H(32)OP(2))]·CH(3)OH, the Rh(I) ion is coordinated by a naphthyl group of a partially oxidized 2,2′-bis­(diphenyl­phosphan­yl)-1,1′-binaphthyl (BINAP) ligand in a η(4) mode, one P atom of the diphenyl­phosphanyl group and one Cl atom. The P=O group does not inter­act with the Rh(I) ion but accepts an O—H⋯O hydrogen bond from the methanol solvent mol­ecule. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3297224/ /pubmed/22412414 http://dx.doi.org/10.1107/S1600536812003418 Text en © Meissner et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meissner, Antje
Selle, Carmen
Drexler, Hans-Joachim
Heller, Detlef
(+)-Chlorido[(1,2,3,4-η;κP (2′))-2′-diphenyl­phosphanyl-2-diphenyl­phosphoryl-1,1′-binaphth­yl]rhodium(I) methanol monosolvate
title (+)-Chlorido[(1,2,3,4-η;κP (2′))-2′-diphenyl­phosphanyl-2-diphenyl­phosphoryl-1,1′-binaphth­yl]rhodium(I) methanol monosolvate
title_full (+)-Chlorido[(1,2,3,4-η;κP (2′))-2′-diphenyl­phosphanyl-2-diphenyl­phosphoryl-1,1′-binaphth­yl]rhodium(I) methanol monosolvate
title_fullStr (+)-Chlorido[(1,2,3,4-η;κP (2′))-2′-diphenyl­phosphanyl-2-diphenyl­phosphoryl-1,1′-binaphth­yl]rhodium(I) methanol monosolvate
title_full_unstemmed (+)-Chlorido[(1,2,3,4-η;κP (2′))-2′-diphenyl­phosphanyl-2-diphenyl­phosphoryl-1,1′-binaphth­yl]rhodium(I) methanol monosolvate
title_short (+)-Chlorido[(1,2,3,4-η;κP (2′))-2′-diphenyl­phosphanyl-2-diphenyl­phosphoryl-1,1′-binaphth­yl]rhodium(I) methanol monosolvate
title_sort (+)-chlorido[(1,2,3,4-η;κp (2′))-2′-diphenyl­phosphanyl-2-diphenyl­phosphoryl-1,1′-binaphth­yl]rhodium(i) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297224/
https://www.ncbi.nlm.nih.gov/pubmed/22412414
http://dx.doi.org/10.1107/S1600536812003418
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AT drexlerhansjoachim chlorido1234ēkp22diphenylphosphanyl2diphenylphosphoryl11binaphthylrhodiumimethanolmonosolvate
AT hellerdetlef chlorido1234ēkp22diphenylphosphanyl2diphenylphosphoryl11binaphthylrhodiumimethanolmonosolvate

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