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μ(3)-Bromido-oxidotri-μ(3)-sulfido-tris(triphenylphosphane-κP)tricopper(I)tungsten(VI)
The title complex, [Cu(3)WBrOS(3)(C(18)H(15)P)(3)], a neutral heavily distorted cubane-like W/S/Cu cluster, was self-assembled from ammonium trithiotungstate(VI), cuprous bromide and triphenylphosphane in N,N-dimethylformamide. The average Cu—Br, Cu—S and W—μ(3)-S bond lengths are 2.731 (2), 2.31...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297238/ https://www.ncbi.nlm.nih.gov/pubmed/22412428 http://dx.doi.org/10.1107/S1600536812004631 |