{μ-5-[1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazolium-2-yl]-2-(2-oxoethenyl-1κC (1))furan-3-yl-2κC (3)}-μ-hydrido-bis(tetra­carbonyl­rhenium) tetra­hydro­furan 0.67-solvate

The title complex, [Re(2)(C(27)H(25)N(2)O(2))H(CO)(8)]·0.67C(4)H(8)O, was formed as a product in the reaction of a rhenium(I)–Fischer carbene complex with a free NHC carbene. The coordination environment about the two Re atoms is slightly distorted octahedral, including a bridging H atom. The imidaz...

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Detalles Bibliográficos
Autores principales: Landman, Marilé, van Westhuizen, Belinda, Bezuidenhout, Daniela I., Liles, David C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297260/
https://www.ncbi.nlm.nih.gov/pubmed/22412450
http://dx.doi.org/10.1107/S1600536812006587

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297260/
https://www.ncbi.nlm.nih.gov/pubmed/22412450
http://dx.doi.org/10.1107/S1600536812006587

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