{μ-5-[1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazolium-2-yl]-2-(2-oxoethenyl-1κC (1))furan-3-yl-2κC (3)}-μ-hydrido-bis(tetra­carbonyl­rhenium) tetra­hydro­furan 0.67-solvate

The title complex, [Re(2)(C(27)H(25)N(2)O(2))H(CO)(8)]·0.67C(4)H(8)O, was formed as a product in the reaction of a rhenium(I)–Fischer carbene complex with a free NHC carbene. The coordination environment about the two Re atoms is slightly distorted octahedral, including a bridging H atom. The imidaz...

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Autores principales: Landman, Marilé, van Westhuizen, Belinda, Bezuidenhout, Daniela I., Liles, David C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297260/
https://www.ncbi.nlm.nih.gov/pubmed/22412450
http://dx.doi.org/10.1107/S1600536812006587
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author Landman, Marilé
van Westhuizen, Belinda
Bezuidenhout, Daniela I.
Liles, David C.
author_facet Landman, Marilé
van Westhuizen, Belinda
Bezuidenhout, Daniela I.
Liles, David C.
author_sort Landman, Marilé
collection PubMed
description The title complex, [Re(2)(C(27)H(25)N(2)O(2))H(CO)(8)]·0.67C(4)H(8)O, was formed as a product in the reaction of a rhenium(I)–Fischer carbene complex with a free NHC carbene. The coordination environment about the two Re atoms is slightly distorted octahedral, including a bridging H atom. The imidazolium and furan groups are almost coplanar, whereas the mesityl substituents show an almost perpendicular arrangement with respect to both heterocyclic units. Mol­ecules of the complex pack in such a way as to form channels parallel with the bc unit-cell face diagonal running through the unit face diagonal. These channels are partially occupied by tetra­hydro­furan solvent mol­ecules.
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spelling pubmed-32972602012-03-12 {μ-5-[1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazolium-2-yl]-2-(2-oxoethenyl-1κC (1))furan-3-yl-2κC (3)}-μ-hydrido-bis(tetra­carbonyl­rhenium) tetra­hydro­furan 0.67-solvate Landman, Marilé van Westhuizen, Belinda Bezuidenhout, Daniela I. Liles, David C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Re(2)(C(27)H(25)N(2)O(2))H(CO)(8)]·0.67C(4)H(8)O, was formed as a product in the reaction of a rhenium(I)–Fischer carbene complex with a free NHC carbene. The coordination environment about the two Re atoms is slightly distorted octahedral, including a bridging H atom. The imidazolium and furan groups are almost coplanar, whereas the mesityl substituents show an almost perpendicular arrangement with respect to both heterocyclic units. Mol­ecules of the complex pack in such a way as to form channels parallel with the bc unit-cell face diagonal running through the unit face diagonal. These channels are partially occupied by tetra­hydro­furan solvent mol­ecules. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297260/ /pubmed/22412450 http://dx.doi.org/10.1107/S1600536812006587 Text en © Landman et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Landman, Marilé
van Westhuizen, Belinda
Bezuidenhout, Daniela I.
Liles, David C.
{μ-5-[1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazolium-2-yl]-2-(2-oxoethenyl-1κC (1))furan-3-yl-2κC (3)}-μ-hydrido-bis(tetra­carbonyl­rhenium) tetra­hydro­furan 0.67-solvate
title {μ-5-[1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazolium-2-yl]-2-(2-oxoethenyl-1κC (1))furan-3-yl-2κC (3)}-μ-hydrido-bis(tetra­carbonyl­rhenium) tetra­hydro­furan 0.67-solvate
title_full {μ-5-[1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazolium-2-yl]-2-(2-oxoethenyl-1κC (1))furan-3-yl-2κC (3)}-μ-hydrido-bis(tetra­carbonyl­rhenium) tetra­hydro­furan 0.67-solvate
title_fullStr {μ-5-[1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazolium-2-yl]-2-(2-oxoethenyl-1κC (1))furan-3-yl-2κC (3)}-μ-hydrido-bis(tetra­carbonyl­rhenium) tetra­hydro­furan 0.67-solvate
title_full_unstemmed {μ-5-[1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazolium-2-yl]-2-(2-oxoethenyl-1κC (1))furan-3-yl-2κC (3)}-μ-hydrido-bis(tetra­carbonyl­rhenium) tetra­hydro­furan 0.67-solvate
title_short {μ-5-[1,3-Bis(2,4,6-trimethyl­phen­yl)-3H-imidazolium-2-yl]-2-(2-oxoethenyl-1κC (1))furan-3-yl-2κC (3)}-μ-hydrido-bis(tetra­carbonyl­rhenium) tetra­hydro­furan 0.67-solvate
title_sort {μ-5-[1,3-bis(2,4,6-trimethyl­phen­yl)-3h-imidazolium-2-yl]-2-(2-oxoethenyl-1κc (1))furan-3-yl-2κc (3)}-μ-hydrido-bis(tetra­carbonyl­rhenium) tetra­hydro­furan 0.67-solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297260/
https://www.ncbi.nlm.nih.gov/pubmed/22412450
http://dx.doi.org/10.1107/S1600536812006587
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