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{μ-5-[1,3-Bis(2,4,6-trimethylphenyl)-3H-imidazolium-2-yl]-2-(2-oxoethenyl-1κC (1))furan-3-yl-2κC (3)}-μ-hydrido-bis(tetracarbonylrhenium) tetrahydrofuran 0.67-solvate
The title complex, [Re(2)(C(27)H(25)N(2)O(2))H(CO)(8)]·0.67C(4)H(8)O, was formed as a product in the reaction of a rhenium(I)–Fischer carbene complex with a free NHC carbene. The coordination environment about the two Re atoms is slightly distorted octahedral, including a bridging H atom. The imidaz...
Autores principales: | Landman, Marilé, van Westhuizen, Belinda, Bezuidenhout, Daniela I., Liles, David C. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297260/ https://www.ncbi.nlm.nih.gov/pubmed/22412450 http://dx.doi.org/10.1107/S1600536812006587 |
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