Efficient oxidation of oleanolic acid derivatives using magnesium bis(monoperoxyphthalate) hexahydrate (MMPP): A convenient 2-step procedure towards 12-oxo-28-carboxylic acid derivatives

A new, straightforward and high yielding procedure to convert oleanolic acid derivatives into the corresponding δ-hydroxy-γ-lactones, by using the convenient oxidizing agent magnesium bis(monoperoxyphthalate) hexahydrate (MMPP) in refluxing acetonitrile, is reported. In addition, a two-step procedur...

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Detalles Bibliográficos
Autores principales: Salvador, Jorge A R, Moreira, Vânia M, Pinto, Rui M A, Leal, Ana S, Paixão, José A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3302076/
https://www.ncbi.nlm.nih.gov/pubmed/22423283
http://dx.doi.org/10.3762/bjoc.8.17

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3302076/
https://www.ncbi.nlm.nih.gov/pubmed/22423283
http://dx.doi.org/10.3762/bjoc.8.17

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