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Fluorescent hexaaryl- and hexa-heteroaryl[3]radialenes: Synthesis, structures, and properties

The syntheses of three new [3]radialenes – hexakis(3,5-dimethylpyrazolyl)-, hexakis(3-cyanophenyl)-, and hexakis(3,4-dicyanophenyl)[3]radialene (1–3) – are reported. Compound 3 is obtained in five steps with an excellent yield of 76% in the key step. Compared to that, the respective steps of the syn...

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Detalles Bibliográficos
Autores principales: Avellaneda, Antonio, Hollis, Courtney A, He, Xin, Sumby, Christopher J
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3302100/
https://www.ncbi.nlm.nih.gov/pubmed/22423273
http://dx.doi.org/10.3762/bjoc.8.7