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Electrochemical generation of 2,3-oxazolidinone glycosyl triflates as an intermediate for stereoselective glycosylation

Glycosyl triflates with a 2,3-oxazolidinone protecting group were generated from thioglycosides by low-temperature electrochemical oxidation. The glycosyl triflates reacted with alcohols to give the corresponding glycosides β-selectively at low temperatures. However, α-selectivity was observed in th...

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Detalles Bibliográficos
Autores principales: Nokami, Toshiki, Shibuya, Akito, Saigusa, Yoshihiro, Manabe, Shino, Ito, Yukishige, Yoshida, Jun-ichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3326625/
https://www.ncbi.nlm.nih.gov/pubmed/22509217
http://dx.doi.org/10.3762/bjoc.8.52